2，6-二异丙基苯酰亚胺 新值二烯双己基叔丁醇钼
2,6-Diisopropylphenyl-imidoneophylidene molybdenum(VI) bis(hexafluoro-t-butoxide) SCHROCK'S CATALYST
分子式: Mo(C₁₀H₁₂)(C₁₂H₁₇N)[OC(CH₃)(CF₃)₂]
分子量: 765.53
纯度: null
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基本信息
安全信息
存储条件Freezer -20℃ |
化学和物理性质
产品描述
Technical Notes:
1. Unlike Mo(C oH12)(C 12H1N)(OC4Ho)2. the bis(hexafluoro-t butoxide) (MoFo) derivative will metathesize many ordinary olefins, especially terminal olefins, and will ROMP many norbornene or substituted norbornadiene monomers to give all cis, and often isotactic, polymers.
2.Useful for the "ring closing" of dienes or the coupling of terminal olefins.
3.Useful for cross-metathesis of alphatic alkenes with 2-vinyl aromatics.
References:
1. J. Am. Chem. Soc., 1994, 116, 3414.
2. J.Am. Chem. Soc.. 1993, 115, 4413.
3. J.Am. Chem .Soc..1992, 114, 5426
4.J. Am chem. Soc .,1992.114.7324.
5. Tetrahedron, 1998. 54, 4413. (review article)
6. J. Mol. Catal. Chem., 2002, 190, 45.
